There have been eight Ambassadors from the People's Republic of China to Angola:
| Name | Appointed | Terminated |
|---|---|---|
| Zhao Zhenkui | September 1984 | May 1988 |
| Hu Lipeng | May 1988 | April 1992 |
| Zhang Baosheng | June 1992 | July 1994 |
| Xiao Sijin | March 1995 | February 1999 |
| Jiang Yuande | February 1999 | August 2002 |
| Zhang Beisan | September 2002 | April 2005 |
| Zhang Bolun | May 2008 | July 2011 |
| Gao Kexiang | July 2011 | Present |